International SI volt transfer experiment

## Intro

Every measurement need a known reference point. How do we know that one second is really a second? How do we know that one meter is indeed 1 meter, not 990 mm or 1010 mm? Science about measurements is called metrology. This is important aspect of any engineering application, be it electronics, machining, analytics and even biology and chemistry. Because of this science we can be sure, that ruler from shop in USA and ruler from shop in Europe or Asia is same. Same applies to electric measurements, such as voltage, current, frequency and resistance.

## Uncertainty and calibration concepts

Measurements of any physical quantity or value can never be exact. One can only know its value with a range of uncertainty. If measurement provides some quantity A, the measurement is written with an uncertainty: A ± ΔA. This expresses that the actual value of A is somewhere between A – ΔA and A + ΔA.

### Resolution versus accuracy

Let’s go some precision hunting. Some might confuse measurement resolution with measurement accuracy. These concepts are two actually different things and can be measured and expressed independently. Imagine yourself shooting a target with arrows. One hit is one measurement sample. If we take just one sample, we cannot know how accurate is it. But if we make a series of samples, we can see much more.

On target case a we have low resolution and low accuracy, with shots all over the place. We cannot clearly see what is real value. Need improve both resolution and accuracy to get sample hits like on target b. This is high resolution with high accuracy. Now if we still use high resolution, but our accuracy is low, we will get target image c. That’s why calibration even more important for high-precision equipment, as even if we have high precision, it does not automatically get good accuracy as well.

There is one more case missing on targets above – with low resolution, and high accuracy. If you got concept right, you should know how it should look like, and feel free to share your thought in comments!

## SI volt history

The volt is the derived unit for electric potential, electric potential difference (voltage), and EMF. The volt is named in honour of the Alessandro Volta, who invented the voltaic pile, possibly the first chemical battery. History of electrical values

https://en.wikipedia.org/wiki/Volt

## Today’s technology

### The Josephson Voltage Standard

Josephson effect is a super conducting physical phenomenon that relates voltage to frequency through the ratio of fundamental constants. It was discovered in 1962, by 22-year old Brian D. Josephson. A Josephson array, using an integrated circuit with number of Josephson junctions, is an intrinsic, independently reproducible standard that is used to represent rather than realize the SI volt. The output voltage of a single Josephson junction is defined as:

• VJ = Junction voltage
• ƒ = Frequency in GHz
• e = elementary charge (1.60217662 × 10-19 coulombs)
• h = Planck’s constant (6.62607004 × 10-34 m2 kg/s)
• n = a positive or negative integer

Today h/2e is called Josephson constant, KJ-90, which is defined as 483597.9 GHz/V. By means of Josephson junctions, voltage can be reproduced with relative uncertainties of less than one part in ten billion (1 : 1010, i.e. 1 nV at 10 V). Since we already have achieved much better uncertainty at 10-16 levels for frequency, and rest of parameters in formula are physics constants, voltage standards based on Josephson arrays today are widely used as national Volt standard worldwide.

Example voltage standard system using this effect is one developed by PTB in Germany. This system consists of a 75 GHz Gunn-oscillator, locked by a PLL to a Fluke 910R, a GPS-controlled Rhubidium Frequency Standard. During operation, the probe with JJA circuit is immersed in a 42 litre dewar vessel with liquid helium to maintain constant temperature at ~4.2K.

AC quantum voltmeter JJA-based voltmeter system with accuracy ±0.001ppm at 10VDC and 0.2ppm at 20VACpk-pk 1kHz.

### The Quantum Hall Resistance Standard

The Quantum Hall effect provides a universal standard for electrical resistance that is theoretically based on only the Planck constant h and the electron charge e. Currently, this standard is implemented in GaAs/AlGaAs. In particular, the Hall resistance can be accurately quantized to within 1 × 10−9 over a 10 T wide range of magnetic flux density, down to 3.5 T, at a temperature of up to few K or with a current of up to 0.5 mA. The Quantum Hall effect comprises the quantization of the Hall resistance in two-dimensional electron systems in rational fractions of R(K) = = 25,812.807557 Ω, the resistance quantum. Despite 30 years of research into the Quantum Hall effect, the level of precision necessary for metrology, which is few ppb, has been achieved only in silicon and III-V heterostructure type devices.
There are also new designs and development to implement QHR using graphene, such as this study.

But all this marvelous gear is not accesible for average hobbyist level, so next best solution would be using good solid-state reference (SSR) with frequent cross-comparison between known calibrated standards. And best candidate for such a device would be Linear LTZ1000-based ultra-zener reference module, to provide very stable and low-noise output. Size of final assembly can be kept small, allowing cheap shipping overseas and project cost while bit high (300-350\$ in parts) is still within reach of any serious volt-nut.

## Practical experiment theory

Most accurate piece of voltage source/measurement gear I have up to this date is old repaired Keithley 2001 7½-digit DMM, later calibrated by Tektronix in February 2014, 2 years ago. Uncertainty of Tektronix calibration facility for 10V in Taiwan is ± 20 ppm. This accuracy level is not suitable for proper HP 3458A calibration. Even if my 2001 still stay precisely spot on it’s calibration, it’s own readings accuracy is 7+4ppm for 24 hours, with ADC’s linearity 2 ppm max.

This experiment is attempt to “import” calibration from known stable source, Fluke 732B, located in USA into my own home-lab, here in Taiwan. To perform this task, best solid-state reference will be used, Linear LTZ1000A, in form of HP 3458A’s opt-002 voltage reference A9 module. This reference module specified to be stable within 4 ppm/year window.

Idea is simple: get absolute voltage output of LTZ module, using Fluke 732B and calibrated HP 3458A as null-meter. This will allow to get voltage reading with 2ppm accuracy. Second step would be sending this LTZ module overseas using airmail to here.

Then I will use my 10V sources and my calibrated Keithley 182M nV-meter to calibrate my 10V sources, to get exactly same voltage difference, as we got with Fluke732B-LTZ. LTZ module temperature will be matched to ambient temperature with ±0.01°C tolerance. This is assuming that voltage output of LTZ itself did not change from shipping and stress.

Then HP 3458A would be calibrated using adjusted 10V sources, to import volt into it’s own reference. If everything goes well, direct reading of LTZ1000 module should then match expected 7.18460898 V.

Also transfer LTZ1000A voltage would be compared to three other LTZ1000-based modules, to get absolute voltage delta of those as well, using HP 3458A or K182M as null-meter. This, and monitoring in future would allow us to ensure that all four LTZ units stay stable over time.

## DCV Source reference setup

Known voltage source is provided by one of our readers, precision enthusiast located in USA. Recently calibrated HP 3458A was used together with uncalibrated Fluke 732B as primary standard.

Here’s our voltage transfer module, HP 03458-66509 A9 PCBA module. This module is designed for use in 8ppm/year stable HP 3458A DMM. It is almost exact copy of Linear LTZ1000 reference schematics, with use of three Vishay Precision Group metal foil resistors and providing direct 7V zener output.

Module was installed in metal cast box to provide some shielding and isolate module itself from ambient airflow. Box was covered with some rags and located at one of 3458A’s.

Initial TC estimation is -0.603ppm/K.

## Experiment execution

LTZ PCBA shipped from source location February 28, 2016 by regular USPS envelope mail.

Regular mail with hard packet and usual ESD bag was used for reference module, nothing fancy at all. LTZ PCBA received at destination location March 17, 2016, which makes 19 days in travel. This is a serious stretch for most of battery operated LTZ1000-based SSR’s if shipped hot (powered). Even if faster FedEx or DHL service used, travel time for international USA-Taiwan package would be still close to 6-8 days.

I prepared connector jig to avoid soldering and thermal stress on reference module, using common 0.1” pin header and Ethernet UTP CAT6 shielded cable. Heater and reference supply was routed by two separate wires to Keithley 2400, configured for +15.000V source with 105mA current compliance. Copper spade lugs are used to ensure low thermal EMF. They were cleaned with sandpaper right before connecting to DMM’s binding posts, to prevent copper oxide from ruining accuracy.

Reference module installed in metal cast box with insulation layers to have smooth and controlled temperature environment. Bottom surface of metal box is attached to 55W TEC module, which is cooled by external fansink. Reference box is further enclosed in styrofoam box with 10mm walls to reduce environment impact and allow better temperature regulation.

Black/white twisted cable is from Honeywell HEL-705 platinum 1KΩ RTD. One is fixed on metal wall, routed to temperature sense input on Keithley 2510 as feedback. Second is fixed on foam box right above the LTZ1000A zener IC, and routed to Keithley 2002 for relative temperature measurement.

Temperature controlled by precision TEC SMU, Keithley 2510 which is well able to maintain temperatures within 0.01°C on this setup. This arrangement was tested multiple times before and allow to control temperatures in range from +18°C to +60°C with ease. After everything set, reference output is connected to HP 3458A for initial direct measurements:

Initial datalog started:

Keithley 2001 used as old standard hooked in parallel as well:

Since now we know exact transfer voltage reference at +23.4°C temperature, first easy step is to check absolute accuracy of DMMs I already have here.

Instrument under test Reading/compare Error, ppm/REF Conditions Last calibrated
Keithley 2001 7.184756 +20.46 Warmup 24 hours February 2014 by Tektronix
Keithley 2002 #1 Warmup 24 hours 2007
Keithley 2002 #2 Warmup 24 hours 2012
Keithley 182-M Warmup 24 hours 2015
HP 3458A 7.18469035 +11.32 Run 24/7 last 2 months January 2016, to K2001

Retest in May 2016.

Temperature coefficient of A9 board is not viable for measurement in this setup.

Published: May 27, 2016, 12:18 p.m.
Modified: May 27, 2016, 12:20 p.m.